Eichrom’s Resolve PTFE filter is designed to optimize the performance of the radon/thoron stripping algorithm in spectra recording low background alpha/beta spectrometers. This second filter product in Eichrom’s Resolve product line joins the 0.1µm polypropylene filter used for alpha spectroscopy source preparation. The PTFE filters have been demonstrated to provide results superior to either glass fiber or cellulose filters in Canberra’s family of instruments known as the iSeries®, including the iSolo and iMatic counters.
The Eichrom PTFE filters are manufactured to the following specifications.
|Resolve PTFE Filter Properties|
|Diameter||25 mm, 47 mm and 50 mm|
|Reference Pore Size||3.0 µm nominal|
|Thickness||0.15 –0.4 mm thick|
|DOP Efficiency||>99.99 % 0.3 mm @5.33 cm/sec|
|Chemical Compatibility||Resistant to most chemicals and solvents|
|Air Permeability||6 ft3/ft2/min @ 0.5″ H2O minimum|
As confirmed through Eichrom’s ISO9001 Quality Control Plan, the Resolve PTFE Filters have a low radiological background and excellent peak resolution as measured by FWHM. The physical characteristics of the filters make them easy to handle, and the backsides of the filters are labeled with a grid to facilitate correct filter orientation on the air sampling unit (Figure 1).
The table below compares the alpha and beta backgrounds, measured on a gas flow proportional counter, for the Resolve PTFE Filters, cellulose and glass fiber filters. The Resolve filter has a background which is not signficantly different than the instrument background. The glass fiber filter has significant background levels of alpha and beta radioactivity.
|α – alpha Background||β – beta Background|
|Cellulose||0.78 ± 1.12||0.17 ± 1.30|
|Glass Fiber||2.00 ± 1.56||4.52 ± 3.44|
|Resolve PTFE Filter||0.24 ± 0.70||0.31 ± 3.54|
As part of Eichrom’s ISO Certified quality control plan, each lot of PTFE material is tested for 233U and 241Am peak resolution using CeF3 micro-precipitation by counting on an alpha spectrometry system. The peak resolution achievable with the Resolve PTFE filter rivals that of a 0.1 µm polypropylene filter. See the table below for results comparing peak full width at half maximum for Eichrom’s two Resolve Filter products.
|Material Pore Size||FWHM 233U||FWHM 241Am|
|Laminated PTFE||3.0 µm||46.7||40.4|
The Canberra iSeries line of instruments are designed with an algorithm to eliminate the bias caused by naturally occurring alpha emitting daughters of radon and thoron from a counted air filter. The quality of the alpha spectrum is an important factor in the ability of the algorithm to perform correctly. Eichrom’s Resolve PTFE Filter delivers a better alpha spectrum than filters of other material.
In a side-by-side comparison of Resolve PTFE, cellulose and glass fiber filters, each was spiked with a combined 474 dpm 233U and 241Am. The alpha activity due to this spike was measured on an iSolo instrument before and after air containing radon was sampled through the filter. The Resolve PTFE filter allowed the iSolo to measure an 84% recovery, while the cellulose filter resulted in an 8% recovery and the glass fiber resulted in a 47% recovery.
|Filter type||Alpha spike
|Measured before air sampling Alpha (dpm)||Initial % Recovery||Measured after air sampling Alpha (dpm)||% Recovery|
|Cellulose||474||106 ± 3.4||22 %||35.9 ± 20.2||8 %|
|Glass||474||237 ± 5.1||50 %||225 ± 18.8||47 %|
|Resolve PFTE||474||415 ± 6.9||88 %||397.8 ± 14.2||84 %|
Figures 1-3 below show the spectra achieved by the three filter types. The blue lines are the ‘uncompensated’ alpha spectrum and the red spectra are the ‘compensated’ alpha spectra after the removal of the effect of the alpha emitting daughters of radon and thoron.
The Resolve PTFE Filter is available in packages of 50. Contact Eichrom or your local distributor to place an order.
Request part numbers: RP-60-25PTFE3, RP-50-47PTFE3 or RP-50-50PTFE3. Other custom sizes available please contact us for a custom price quotation.